fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ2 O,P]rhenium(I)
نویسندگان
چکیده
The structure of the title complex, [ReBr(C(13)H(19)OP)(CO)(3)], displays a facial coordination of the three CO ligands and a κ(2)O,P coordination mode of the 2-diisopropyl-phosphino-benzaldehyde ligands. The Re-C bond distance for the CO ligand trans to the P atom is, due to its trans influence, elongated to 1.943 (3) Å, showing that this CO ligand is more weakly bound to the Re centre than the other two.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012